Trace Moisture Detection Using Continuous-Wave Cavity RingDown Spectroscopy

We have developed an instrument to measure trace concentrations of small hydride species in gases using continuous-wave cavity ring-down spectroscopy with near-infrared diode laser excitation. An rms baseline equivalent absorbance of 9.2 × 10^-11 cm-1/(check mark)n is found, where n is the number of ring-down transients. When the 1396.376-nm absorption line of water is used, this corresponds to a noise equivalent moisture concentration in nitrogen gas of 68 pptv/(check mark)n. Water vapor concentration is detected over a range extending from 3 to 1000 ppbv and found to depend linearly on the concentration as determined by a calibrated commercial moisture sensor.