Title of article
Solid State Cells with Buffer Electrodes for Measurement of Chemical Potentials and Gibbs Energies of Formation: System Ca-Rh-O
Author/Authors
Waseda، Y. نويسنده , , Jacob، K. T. نويسنده ,
Issue Information
روزنامه با شماره پیاپی سال 2000
Pages
-212
From page
213
To page
0
Abstract
When the alkoxide precursor to Synroc is heated to 800°C in air, a cubic oxide is formed. This phase is shown by X-ray and neutron powder diffraction to have the fluorite (a=4.99 ?) rather than the pyrochlore structure. This has important implications for waste encapsulation
Keywords
phase diagram , system Ca-Rh-O , calcium rhodite , Gibbs energy , Enthalpy , entropy of formation , CaRh2O4 , decomposition temperature
Journal title
JOURNAL OF SOLID STATE CHEMISTRY
Serial Year
2000
Journal title
JOURNAL OF SOLID STATE CHEMISTRY
Record number
56340
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