Title of article
On the Crystal Chemistry and Stability of Sm2+ in SmSO4 and Solid Solutions of M1-xSmxSO4 (M=Ba, Sr)
Author/Authors
Mikhail، P. نويسنده , , Sieber، A. نويسنده , , Samtleben، T. نويسنده , , Trusch، B. نويسنده , , Lüthi، T. نويسنده , , Hulliger، J. نويسنده ,
Issue Information
روزنامه با شماره پیاپی سال 2000
Pages
-534
From page
535
To page
0
Abstract
Solid solution formation of Sm2+ and MSO4 (M=Sr, Ba) was investigated for syntheses using (i) a LiCl high-temperature solution exposed to a reducing atmosphere and (ii) precipitation reactions at room temperature starting from aqueous solutions of SmI2 or electrochemically gained Sm2+. In contrast to (ii), present results show that a high-temperature approach (i) yielded only a very low amount of Sm2+ in M1-xSmxSO4. Formation of a solid solution system (0
Keywords
structural phase transition , Rietveld refinement , lanthanum chromite , neutron powder diffraction
Journal title
JOURNAL OF SOLID STATE CHEMISTRY
Serial Year
2000
Journal title
JOURNAL OF SOLID STATE CHEMISTRY
Record number
56676
Link To Document