Decomposition of EuPdIn and EuPtIn at high temperature and high pressure--formation of the hexagonal Laves phases EuPd0.72In1.28 and EuPt0.56In1.44

The single crystals of the superconducting Li0.2(1)ZrNCl have been derived from the single crystals of BETA-ZrNCl by intercalation of lithium using an n-butyllithium solution in hexane. A The crystal structure has been refined on the basis of the single-crystal X-ray data: the space group R-3m, a=3.591(1) ?, c=27.839(6) ?, Z=6, R1=0.0749 for 196 reflections and 12 variables. BETA-ZrNCl is isotypic with SmSI, while the structure of Li0.2(1)ZrNCl can be described as the Li intercalated YOF type, a stacking variant of the SmSI type. The tightly bound slabs with a Cl-Zr-N-N-Zr-Cl sequence of close-packed layers are stacked rhombohedrally along the c-axis, with the van der Waals gaps between the chlorine layers hosting Li ions. This is the first single-crystal study on the Li intercalated phase. The structural changes from the pristine single crystals were precisely determined.