Title of article
Carrier Doping Effect into Quasi-One-Dimensional Bromo-Bridged Ni(III) Complexes with Strong Electron-Correlation by Cu (II) Ions, [Ni1-xCux(chxn)2Br]Br2-x
Author/Authors
Miyasaka، Hitoshi نويسنده , , Sugiura، Ken-ichi نويسنده , , Yamashita، Masahiro نويسنده , , Iwahori، Fumiyasu نويسنده , , Okamoto، Hiroshi نويسنده , , Kishida، Hideo نويسنده , , Ono، Takashi نويسنده , , Matsunaga، Satoshi نويسنده , , Sasaki، Mari نويسنده , , Takaishi، Shinya نويسنده , , Tanaka، Hisaaki نويسنده ,
Issue Information
روزنامه با شماره پیاپی سال 2003
Pages
-7691
From page
7692
To page
0
Abstract
This communication will describe the electron doping effect into Ni complexes by Cu ions, [Ni1-CUx(chxn)2Br]Br2-x (x = 0.038 and 0.101) by using an electrochemical oxidation method. A drastic increase of electrical conductivity as well as a new absorption band around 0.5 eV in single crystal reflectance spectra was observed by doping Cu ions, indicating the electron doping was successfully made. An ESR result shows unpaired electrons locate in the dx2-y2 orbitals of Cu and have almost no interaction with those of other ions.
Keywords
Mentha , spearmint , peppermint , Verticillium wilt , certification , meristem culture
Journal title
INORGANIC CHEMISTRY
Serial Year
2003
Journal title
INORGANIC CHEMISTRY
Record number
66305
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