Title of article
Structure, Reactivity, and Computational Studies of a Novel Ruthenium Hydrogen Sulfide Dihydride Complex
Author/Authors
Mahon، Mary F. نويسنده , , Chatwin، Sarah L. نويسنده , , Diggle، Richard A. نويسنده , , Jazzar، Rodolphe F. R. نويسنده , , Macgregor، Stuart A. نويسنده , , Whittlesey، Michael K. نويسنده ,
Issue Information
روزنامه با شماره پیاپی سال 2003
Pages
-7694
From page
7695
To page
0
Abstract
Addition of 1 atm of H2S to [Ru(IMes)2(CO)(EtOH)H2] (IMes = 1,3-bis(2,4,6-trimethylphenyl)imidazol-2-ylidene) affords the airstable hydrogen sulfide dihydride complex, [Ru(IMes)2(CO)(H2S)H2] 2. Treatment of 2 with excess H2S leads to formation of the 16-electron bis-hydrosulfido complex, [Ru(IMes)2(CO)(SH)2] 3. Preliminary studies show that 3 reacts with both H2 and CO in solution as well as in the solid state. Both 2 and 3 have been structurally characterized.
Keywords
meristem culture , peppermint , certification , spearmint , Verticillium wilt , Mentha
Journal title
INORGANIC CHEMISTRY
Serial Year
2003
Journal title
INORGANIC CHEMISTRY
Record number
66308
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