• Title of article

    New Routes to High Nuclearity Clusters: Fluoride-Based Octametallic and Tridecametallic Clusters of Manganese

  • Author/Authors

    Teat، Simon J. نويسنده , , Collison، David نويسنده , , Raftery، James نويسنده , , Jones، Leigh F. نويسنده , , Brechin، Euan K. نويسنده ,

  • Issue Information
    روزنامه با شماره پیاپی سال 2003
  • Pages
    -6970
  • From page
    6971
  • To page
    0
  • Abstract
    The reaction of MnF3 with 5,6-dimethylbenzotriazole (Me2BTAH) gives the [MnIII8] complex [Mn8O4(OMe)2(Me2BTA)6F8(Me2BTAH) (MeOH)8] and the [MnIV3MnIII10] complex [Mn13O12(Me2BTA)12F6(MeOH)10(H2O)2]. The octametallic species is an "intermediate" in the formation of the tridecametallic cluster.
  • Keywords
    molecular data , molecular processes , ISM: molecules
  • Journal title
    INORGANIC CHEMISTRY
  • Serial Year
    2003
  • Journal title
    INORGANIC CHEMISTRY
  • Record number

    67030