Title of article
Cupric Decamolybdodivanadophosphate. A Coordination Polymer Heterogeneous Catalyst for Rapid, High Conversion, High Selectivity Sulfoxidation Using the Ambient Environment
Author/Authors
Hill، Craig L. نويسنده , , Anderson، Michelle D. Ritorto and Travis M. نويسنده , , Hardcastle، Kenneth I. نويسنده , , Okun، Nelya M. نويسنده ,
Issue Information
روزنامه با شماره پیاپی سال 2003
Pages
-660
From page
661
To page
0
Abstract
A new type of coordination network polymer involving the redox-active polyanion, PV2Mo10O405-, and bridging -CuII(OH2)4- units, {[(CuII(OH2)4)3 (OH)]PV2Mo10O40}n (1), has been characterized by X-ray crystallography and several other methods. It is the first efficient heterogeneous (insoluble) catalyst for selective and rapid sulfoxidation using only the ambient environment (air at room temperature). Catalytic activity is enhanced by soluble nitrate in nontoxic perfluoropolyether (PFPE) media.
Keywords
Complete oxidation , Metal catalysts , Partial oxidation , Methane oxidation , Oscillations
Journal title
INORGANIC CHEMISTRY
Serial Year
2003
Journal title
INORGANIC CHEMISTRY
Record number
67315
Link To Document