Title of article
Spectroscopic and crystallographic evidence for the N-protonated FeIFeI azadithiolate complex related to the active site of Fe-only hydrogenases
Author/Authors
Li، Guanghua نويسنده , , Wang، Qing Mei نويسنده , , Liu، Xiaoyang نويسنده , , Sun، Licheng نويسنده , , Akermark، Bjorn نويسنده , , Wang، Fujun نويسنده , , Jin، Kun نويسنده , , Dong، Weibing نويسنده ,
Issue Information
روزنامه با شماره پیاپی سال 2005
Pages
-3220
From page
3221
To page
0
Abstract
The complex [{((mu)-SCH2)2N(CH2C6H4-2-Br)}Fe2(CO)6] and its N-protonated species, as structural models of the Fe-only hydrogenase active site, were identified spectroscopically and crystallographically, and their molecular structures show the 0.04–0.1 (angstrom) lengthening of the three N–C bonds and an intramolecular H...Br contact (2.82 (angstrom)) in the crystalline state of the N-protonated species.
Journal title
CHEMICAL COMMUNICATIONS - LETCHWORTH
Serial Year
2005
Journal title
CHEMICAL COMMUNICATIONS - LETCHWORTH
Record number
68174
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