Title of article
Synthesis of novel axially chiral Rh–NHC complexes derived from BINAM and application in the enantioselective hydrosilylation of methyl ketones
Author/Authors
Shi، Jian-Min نويسنده , , Duan، Wei-Liang نويسنده , , Rong، Guo-Bin نويسنده ,
Issue Information
روزنامه با شماره پیاپی سال 2003
Pages
-2915
From page
2916
To page
0
Abstract
Novel axially chiral Rh N-heterocyclic carbene complexes were prepared from axially dissymmetric 1,1ʹ-binaphthalenyl-2,2ʹ-diamine and applied in the Rh-catalyzed enantioselective hydrosilylation of methyl ketones. The corresponding sec-alcohols can be obtained in high yields with good to excellent ee.
Keywords
pth moment convergence , uniform norm , piecewise linear approximation , fractional Brownian motion , Maxima of Gaussian processes
Journal title
CHEMICAL COMMUNICATIONS - LETCHWORTH
Serial Year
2003
Journal title
CHEMICAL COMMUNICATIONS - LETCHWORTH
Record number
68646
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