Title of article
Stereoselective synthesis of tetrahydropyran-3-ones by rearrangement of oxonium ylides generated from metal carbenoids
Author/Authors
Clark، J. Stephen نويسنده , , Whitlock، Gavin نويسنده , , Jiang، Shende نويسنده , , Onyia، Ngozi نويسنده ,
Issue Information
روزنامه با شماره پیاپی سال 2003
Pages
-2577
From page
2578
To page
0
Abstract
The synthesis of tetrahydropyran-3-ones by copper-catalysed reactions of diazo ketone tethered allylic ethers has been explored. Product distribution can be explained by the intermediacy of a free ylide or direct rearrangement of a metal-bound ylide equivalent.
Keywords
starburstinfrared , evolution galaxies
Journal title
CHEMICAL COMMUNICATIONS - LETCHWORTH
Serial Year
2003
Journal title
CHEMICAL COMMUNICATIONS - LETCHWORTH
Record number
68743
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