Title of article
Diastereoselective titanium-mediated construction of cis-2,3-ring annelated 1-(2-chloroethyl)cyclopropanols
Author/Authors
Lecornué، Frédéric نويسنده , , Ollivier، Jean نويسنده ,
Issue Information
روزنامه با شماره پیاپی سال 2003
Pages
-583
From page
584
To page
0
Abstract
Titanium(IV)-mediated cyclopropanation induced by reaction of cycloalkylmagnesium bromides 1a–e in the presence of titanium tetraisopropoxide with ethyl beta-chloropropionate 2 yielded cis-fused 1-(2ʹ-chloroethyl)cyclopropanols 3b–e with diastereoselectivity highly depending on the ring size. Unexpected rearrangement products 5d,e were isolated in some cases.
Keywords
Riemann zeta function , Mellin transform , characterization of distributions , Bessel process , Levy process , gamma process , Brownian motion , Meixner process
Journal title
CHEMICAL COMMUNICATIONS - LETCHWORTH
Serial Year
2003
Journal title
CHEMICAL COMMUNICATIONS - LETCHWORTH
Record number
69098
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