• Title of article

    The truly symmetrical doubly-bridging mode of trimethylphosphine in a dinuclear rhodium complex

  • Author/Authors

    Werner، Helmut نويسنده , , Pechmann، Thomas نويسنده , , Brandt، Carsten D. نويسنده ,

  • Issue Information
    روزنامه با شماره پیاپی سال 2003
  • Pages
    -1135
  • From page
    1136
  • To page
    0
  • Abstract
    The dinuclear complex [Rh2I2(µ-CPh2)2(µ-PMe3)] was prepared from the Rh2(acac)2 counterpart and Me3SiI and shown crystallographically to contain the PMe3 ligand in a truly symmetrical bridging position; a new synthetic route to migrate more bulky phosphines such as PPh3 and PiPr3 from a terminal into a bridging site is also described.
  • Keywords
    Brownian motion , Mellin transform , Riemann zeta function , characterization of distributions , gamma process , Levy process , Meixner process , Bessel process
  • Journal title
    CHEMICAL COMMUNICATIONS - LETCHWORTH
  • Serial Year
    2003
  • Journal title
    CHEMICAL COMMUNICATIONS - LETCHWORTH
  • Record number

    69252