• Title of article

    Chirality control in 2,2-biphosphole ligand leading to enantiopure Pd complex

  • Author/Authors

    Daran، Jean-Claude نويسنده , , Ortega، Carmen نويسنده , , Gouygou، Maryse نويسنده ,

  • Issue Information
    روزنامه با شماره پیاپی سال 2003
  • Pages
    -1153
  • From page
    1154
  • To page
    0
  • Abstract
    Asymmetric alkylation of the 3,4-dimethyl-5-phenyl-2,2ʹ-biphospholyl anion with the (2R, 4R)-(–)-pentaneditosylate leads to a new chirally flexible 2,2ʹ-biphosphole ligand as a mixture of three diasteroisomers. By complexation with Pd(II), a chirality control occurs to afford enantiopure Pd complex.
  • Keywords
    Levy process , Bessel process , gamma process , Riemann zeta function , Mellin transform , Brownian motion , characterization of distributions , Meixner process
  • Journal title
    CHEMICAL COMMUNICATIONS - LETCHWORTH
  • Serial Year
    2003
  • Journal title
    CHEMICAL COMMUNICATIONS - LETCHWORTH
  • Record number

    69279