Title of article
Cationic benzyl zirconium heteroscorpionates: synthesis and characterization of a novel ethylene polymerisation catalyst showing an unusual temperature dependent polymerisation mechanism
Author/Authors
Milione، Stefano نويسنده , , Montefusco، Cosimo نويسنده , , Cuenca، Tomas نويسنده , , Grassi، Alfonso نويسنده ,
Issue Information
روزنامه با شماره پیاپی سال 2003
Pages
-1175
From page
1176
To page
0
Abstract
The reaction of (bpzmp)Zr(CH2Ph)3 with B(C6F5)3 produces the active ethylene polymerisation catalyst [(bpzmp)Zr(CH2Ph)2]+[PhCH2B(C6F5)3]– which showed a temperature dependent polymerisation mechanism identified by variable temperature 1H NMR analysis of the catalyst solution.
Keywords
Brownian motion , Bessel process , Levy process , gamma process , Meixner process , Mellin transform , characterization of distributions , Riemann zeta function
Journal title
CHEMICAL COMMUNICATIONS - LETCHWORTH
Serial Year
2003
Journal title
CHEMICAL COMMUNICATIONS - LETCHWORTH
Record number
69312
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