Title of article
New examples of metalloaromatic Al-clusters: (Al4M4)Fe(CO)3(M = Li, Na and K) and (Al4M4)2Ni: rationalization for possible synthesis
Author/Authors
Datta، Ayan نويسنده , , Pati، Swapan K. نويسنده ,
Issue Information
روزنامه با شماره پیاپی سال 2005
Pages
-5031
From page
5032
To page
0
Abstract
Ab initio calculations reveal that all-metal antiaromatic molecules like Al4M4(M = Li, Na and K) can be stabilized in half sandwich (Al4M4)Fe(CO)3 and full sandwich (Al4M4)2Ni complexes. The formation of the full sandwich complex [(Al4M4)2Ni] from its organometallic precursor depends on the stability of the organic– inorganic hybrid (C4H4)Ni(Al4Li4).
Keywords
molecular data , ISM: molecules , molecular processes
Journal title
CHEMICAL COMMUNICATIONS - LETCHWORTH
Serial Year
2005
Journal title
CHEMICAL COMMUNICATIONS - LETCHWORTH
Record number
69597
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