Title of article
Selective formation of a stable (mu)-peroxo ferric heme-Cu II complex from the corresponding (mu)-oxo Fe III –Cu II species with hydrogen peroxide
Author/Authors
Naruta، Yoshinori نويسنده , , Tani، Fumito نويسنده , , Chishiro، Takefumi نويسنده , , Shimazaki، Yuichi نويسنده ,
Issue Information
روزنامه با شماره پیاپی سال 2005
Pages
-1078
From page
1079
To page
0
Abstract
An oxo-bridged ferric heme-copper(II) complex, obtained by thermal transformation of the corresponding peroxobridged complex, was reacted with an equimolar amount of H2O2 to regenerate the (mu)-peroxo complex by a ligand exchange from oxo to peroxo, without the formation of a ferryl-oxo species or heme degradation as are observed in general ferric heme-H2O2 reactions.
Keywords
Aphthona czwalinae , Aphthona lacertosa , Aphthona flava , Leafy spurge flea beetles , Spurgia esulae , Aphthona nigriscutis , IPM , Invasive weeds , Biological control , Endangered species , Euphorbia esula
Journal title
CHEMICAL COMMUNICATIONS - LETCHWORTH
Serial Year
2005
Journal title
CHEMICAL COMMUNICATIONS - LETCHWORTH
Record number
69677
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