Title of article
Reactivity of 2-acylaminoacrylates with ketene diethyl acetal; [2 + 2] cycloadditions vs. tandem condensations
Author/Authors
Avenoza، Alberto نويسنده , , Busto، Jesus H. نويسنده , , Canal، Noelia نويسنده , , Peregrina، Jesus M. نويسنده ,
Issue Information
روزنامه با شماره پیاپی سال 2003
Pages
-1375
From page
1376
To page
0
Abstract
The reactivity of 2-acylaminoacrylates with ketene diethyl acetal can be modulated by means of thermal conditions to yield cyclobutanes for the preparation of protected (beta)-hydroxycyclobutane-(alpha)-amino acids, or catalytic conditions that yield cyclohexanes by tandem condensations to obtain interesting building blocks that are alternatives to Danishefskyʹs diene.
Keywords
isoprene oxidation , atmospheric VOC , inhibition of S(IV) autoxidation , Sulphur dioxide , isoprene
Journal title
CHEMICAL COMMUNICATIONS - LETCHWORTH
Serial Year
2003
Journal title
CHEMICAL COMMUNICATIONS - LETCHWORTH
Record number
69873
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