Title of article
Microporous chiral metal coordination polymers: hydrothermal synthesis, channel engineering and stability of lanthanide tartrates
Author/Authors
Williams، Ian D. نويسنده , , Thushari، Samadara نويسنده , , Cha، John A. K. نويسنده , , Sung، Herman H.-Y. نويسنده , , Chui، Stephen S.-Y. نويسنده , , Leung، Andy L.-F. نويسنده , , Yen، Yu-Fong نويسنده ,
Issue Information
روزنامه با شماره پیاپی سال 2005
Pages
-5514
From page
5515
To page
0
Abstract
L-Tartrate ions can endure hydrothermal conditions up to 160 °C to form the robust, enantiopure open-framework coordination polymers [Ln2(L-TAR)3(H2O)2]3H2O, 1; the addition of succinate results in formation of the related [Ln2(L-TAR)2(SUC)(H2O)2]5.5H2O, 2 with larger channels than 1, whereas racemic D/L-tartrate gives the more condensed [Ln2(D/L-TAR)3(H2O)2], 3. TAR = [C4H4O6]^2-.
Keywords
molecular processes , molecular data , ISM: molecules
Journal title
CHEMICAL COMMUNICATIONS - LETCHWORTH
Serial Year
2005
Journal title
CHEMICAL COMMUNICATIONS - LETCHWORTH
Record number
70068
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