• Title of article

    Formal encapsulation of [Fe(H2O)6]^3+ by {Fe2(hpdta)} units gives a system of S= 13/2 FeIII9 oxo clusters showing magnetic hysteresis

  • Author/Authors

    Wernsdorfer، Wolfgang نويسنده , , Powell، Annie K. نويسنده , , Anson، Christopher E. نويسنده , , Schmitt، Wolfgang نويسنده ,

  • Issue Information
    روزنامه با شماره پیاپی سال 2005
  • Pages
    -2097
  • From page
    2098
  • To page
    0
  • Abstract
    Under solvothermal conditions the unprecedented nonanuclear FeIII aggregate [Fe9((mu)3-O)4((mu)-OH)4(hpdta)4]5– is formed through the formal encapsulation of [Fe(H2O)6]3+ by four [Fe2(hpdta)(H2O)2]+ units: the aggregates have ground state spins of S= 13/2 while the observed hysteresis below 1.8 K results from inter-cluster antiferromagnetic coupling.
  • Keywords
    PLAYBACK EXPERIMENTS , TONIC COMMUNICATION , URGENCY-BASED , VIGILANCE
  • Journal title
    CHEMICAL COMMUNICATIONS - LETCHWORTH
  • Serial Year
    2005
  • Journal title
    CHEMICAL COMMUNICATIONS - LETCHWORTH
  • Record number

    70268

    • Link To Document
    https://search.isc.ac/dl/search/defaultta.aspx?DTC=10&DC=70268