Title of article
Organolithium-mediated conversion of (beta)-functionalised aziridines into alkynyl amino alcohols and diamines
Author/Authors
OBrien، Peter نويسنده , , Huang، Jianhui نويسنده ,
Issue Information
روزنامه با شماره پیاپی سال 2005
Pages
-5695
From page
5696
To page
0
Abstract
The direct conversion of dihydrofuran and dihydropyrrole N-triisopropylbenzenesulfonyl aziridines into alkynyl amino alcohols and diamines respectively can be achieved using 3 equiv. sec-butyllithium–PMDETA in THF; use of n-butyllithium and (–)-sparteine in Et2O gave an alkynyl amino alcohol in 60% ee.
Keywords
molecular processes , molecular data , ISM: molecules
Journal title
CHEMICAL COMMUNICATIONS - LETCHWORTH
Serial Year
2005
Journal title
CHEMICAL COMMUNICATIONS - LETCHWORTH
Record number
70271
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