Geochemical record of the Holocene Jomon transgression and human activity in coastal lagoon sediments of the Sanʹin district, SW Japan

Coastal lagoon muds were analyzed to evaluate changes in sedimentary environments by the Jomon transgression from the lower to middle Holocene age and human activities. Core samples from Lake Shinji, Southwest Japan were utilized, which cover the entire Holocene Nakaumi Formation (ca. 23-m thick), and comprise the Lower, Middle, Upper and Uppermost members. Total sulfur (TS) contents and Fe2O3/Al2O3 ratios increase from the boundary of Middle and Upper members, which is 1 m below the Kikai-Akahoya (K-Ah) volcanic ash of 6300 years BP. This change coincides to the pollen flora zone boundary of the Pinus–Abies and the Cyclobalanopsis–Castanopsis, suggesting transition to a warming climate. Chemical index of alteration (CIA) values [(ratio of Al to Al+Ca+Na+K)×100] and Rb/K ratios also show gradual increase from the middle part of the Upper member, due to its derivation from highly weathered source material probably formed under warming and rainy condition. Al2O3/TiO2 and SiO2/TiO2 show little variation from the Lower to the Upper members, probably related to consistent feldspar composition in the source rocks, and homogeneously mixed clays. In the Uppermost member (from 1500 years), sharp increases in Ti/Zr and decreases in both Nb/Y and Zr/Y occurred, suggesting heavy mineral fractionation. This change was caused by iron sand processing called Kannanagashi and charcoal-making in the most mountainous regions. Soil erosion by these processes brought changes in mud composition, shown by the enrichment in Al2O3, and depletion in Zr and Cr. Human activities thus had severe impacts on sedimentary environments compared with the natural changes since the Jomon transgression.