Title of article
[LnIIAlIII2(alkyl)8]x: donor addition instead of donor-induced cleavage
Author/Authors
Anwander، Reiner نويسنده , , Dietrich، H. Martin نويسنده , , Schrems، Marcus G. نويسنده , , Tornroos، Karl W. نويسنده ,
Issue Information
روزنامه با شماره پیاپی سال 2005
Pages
-5921
From page
5922
To page
0
Abstract
(SmAl2Me8)x and (SmAl2Et8)x are obtained via a silylamide elimination reaction from Sm[N(SiMe3)2]2(THF)2 and excess AlR3 (R = Me, Et); (LnAl2Et8)x(Ln = Sm, Yb) react with THF, pyridine, and 1,10-phenanthroline to form the first donor adducts of homoleptic peralkylated Ln–Al heterobimetallic complexes.
Keywords
molecular processes , ISM: molecules , molecular data
Journal title
CHEMICAL COMMUNICATIONS - LETCHWORTH
Serial Year
2005
Journal title
CHEMICAL COMMUNICATIONS - LETCHWORTH
Record number
70474
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