Title of article
Total synthesis of viridiofungin A
Author/Authors
Ishihara، Jun نويسنده , , Morokuma، Kenji نويسنده , , Takahashi، Keisuke نويسنده , , Hatakeyama، Susumi نويسنده ,
Issue Information
روزنامه با شماره پیاپی سال 2005
Pages
-2264
From page
2265
To page
0
Abstract
Viridiofungin A, a member of amino alkyl citrate antibiotics from Trichoderma viride, was enantioselectively synthesized in naturally occurring form for the first time, employing regio- and stereoselective opening of the chiral glycidate with vinylmagnesium bromide and alkene cross metathesis of the citric acid core and hexadec-15-en-8-one as key steps.
Keywords
Ti-MCM-41 , Synthesis of (beta)-amino alcohols , Aminolysis of epoxides , Titanosilicate molecular sieves
Journal title
CHEMICAL COMMUNICATIONS - LETCHWORTH
Serial Year
2005
Journal title
CHEMICAL COMMUNICATIONS - LETCHWORTH
Record number
70579
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