Title of article
Demethylation of the [Me3Sn(PhN2O2)]4 tetramer into dimeric [Me2Sn(PhN2O2)2]2: a thermally induced methyl-transfer between supramolecules
Author/Authors
Deak، Andrea نويسنده , , Tarkanyi، Gabor نويسنده ,
Issue Information
روزنامه با شماره پیاپی سال 2005
Pages
-4073
From page
4074
To page
0
Abstract
The single crystals of tetrameric [Me3Sn(PhN2O2)]4(1) supramolecule demethylates into single crystals of [Me2Sn(PhN2O2)2]2 dimer (2) and volatile Me4Sn, as a result of a crystal-to-crystal supramolecular structural transformation, which occurs upon heating and it is accompanied by a significant change of the molecular and crystal structures.
Keywords
Synthesis of (beta)-amino alcohols , Aminolysis of epoxides , Ti-MCM-41 , Titanosilicate molecular sieves
Journal title
CHEMICAL COMMUNICATIONS - LETCHWORTH
Serial Year
2005
Journal title
CHEMICAL COMMUNICATIONS - LETCHWORTH
Record number
70621
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