Title of article
Synthesis and catalytic activity of a chiral periodic mesoporous organosilica (ChiMO)
Author/Authors
Corma، Avelino نويسنده , , Baleiz?o، Carlos نويسنده , , Gigante، Barbara نويسنده , , Das، Debasish نويسنده , , Alvaro، Mercedes نويسنده , , Garcia، Hermenegildo نويسنده ,
Issue Information
روزنامه با شماره پیاپی سال 2003
Pages
-185
From page
186
To page
0
Abstract
A chiral vanadyl salen complex having two peripheral trimethoxysilyl groups has been used to obtain a chiral periodic mesoporous organosilica having MCM-41 periodicity and the two Si–CH2 groups anchored on the framework; this solid induces 30 % enantioselectivity in the cyanosilylation of benzaldehyde.
Keywords
isoprene oxidation , Sulphur dioxide , inhibition of S(IV) autoxidation , isoprene , atmospheric VOC
Journal title
CHEMICAL COMMUNICATIONS - LETCHWORTH
Serial Year
2003
Journal title
CHEMICAL COMMUNICATIONS - LETCHWORTH
Record number
70664
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