Title of article
A long-range chiral relay via tertiary amide group in asymmetric catalysis: new amino acid-derived N,P-ligands for copper-catalysed conjugate addition
Author/Authors
Malkov، Andrei V. نويسنده , , Hand، John B. نويسنده , , Kocovsk?، Pavel نويسنده ,
Issue Information
روزنامه با شماره پیاپی سال 2003
Pages
-1947
From page
1948
To page
0
Abstract
New N,P-ligands 4–6, derived from valinol and prolinol, respectively, have been developed for the asymmetric, copper(I)catalysed conjugate addition of diethylzinc to unsaturated ketones; the tertiary amide group has been shown to effectively relay the chiral information from the ligand backbone to the active centre.
Keywords
inhibition of S(IV) autoxidation , atmospheric VOC , isoprene , isoprene oxidation , Sulphur dioxide
Journal title
CHEMICAL COMMUNICATIONS - LETCHWORTH
Serial Year
2003
Journal title
CHEMICAL COMMUNICATIONS - LETCHWORTH
Record number
70733
Link To Document