Title of article
A remarkably effective catalyst for the asymmetric transfer hydrogenation of aromatic ketones in water and air
Author/Authors
Ikariya، Takao نويسنده , , Wu، Xiaofeng نويسنده , , Vinci، Daniele نويسنده , , Xiao، Jiangliang نويسنده ,
Issue Information
روزنامه با شماره پیاپی سال 2005
Pages
-4446
From page
4447
To page
0
Abstract
A Rh(III) complex generated in situ from [Cp*RhCl2]2 and (1R,2R)-N-(p-toluenesulfonyl)-1,2-cyclohexanediamine (TsCYDN) serves as a remarkably effective, robust catalyst for the asymmetric transfer hydrogenation of aromatic ketones by HCOONa in water in air, affording alcohols in up to 99% ee.
Keywords
Fenton-like , Oxidation , Carbon-Fe catalysts , H2O2 , Orange II
Journal title
CHEMICAL COMMUNICATIONS - LETCHWORTH
Serial Year
2005
Journal title
CHEMICAL COMMUNICATIONS - LETCHWORTH
Record number
70840
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