Title of article
Reactivity of a 1:1 copper–oxygen complex: isolation of a Cu(II)-o-iminosemiquinonato species
Author/Authors
Tolman، William B. نويسنده , , Reynolds، Anne M. نويسنده , , Lewis، Elizabeth A. نويسنده , , Aboelella، Nermeen W. نويسنده ,
Issue Information
روزنامه با شماره پیاپی سال 2005
Pages
-2013
From page
2014
To page
0
Abstract
While a 1:1 Cu–O2 adduct is generally unreactive with organic substrates, phosphines displace O2via an associative process and added Cu(I) leads to a novel internal ligand oxidation to yield a Cu(II)-o-iminosemiquinone complex.
Keywords
Oxidation , H2O2 , Orange II , Carbon-Fe catalysts , Fenton-like
Journal title
CHEMICAL COMMUNICATIONS - LETCHWORTH
Serial Year
2005
Journal title
CHEMICAL COMMUNICATIONS - LETCHWORTH
Record number
70906
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