• Title of article

    Reactivity of a 1:1 copper–oxygen complex: isolation of a Cu(II)-o-iminosemiquinonato species

  • Author/Authors

    Tolman، William B. نويسنده , , Reynolds، Anne M. نويسنده , , Lewis، Elizabeth A. نويسنده , , Aboelella، Nermeen W. نويسنده ,

  • Issue Information
    روزنامه با شماره پیاپی سال 2005
  • Pages
    -2013
  • From page
    2014
  • To page
    0
  • Abstract
    While a 1:1 Cu–O2 adduct is generally unreactive with organic substrates, phosphines displace O2via an associative process and added Cu(I) leads to a novel internal ligand oxidation to yield a Cu(II)-o-iminosemiquinone complex.
  • Keywords
    Oxidation , H2O2 , Orange II , Carbon-Fe catalysts , Fenton-like
  • Journal title
    CHEMICAL COMMUNICATIONS - LETCHWORTH
  • Serial Year
    2005
  • Journal title
    CHEMICAL COMMUNICATIONS - LETCHWORTH
  • Record number

    70906