Title of article
Guest dechlorination and covalent capture following photoexcitation of inclusion complexes in water
Author/Authors
David A. Williamson، نويسنده , , Anne M. Barenberg، نويسنده , , Carolyn A. Coleman، نويسنده , , David R. Benson، نويسنده ,
Issue Information
روزنامه با شماره پیاپی سال 2000
Pages
4
From page
1443
To page
1446
Abstract
Photoexcitation of complexes between cyclophane 1 and 1- or 2-chloronaphthalene in aqueous solution leads to rapid dechlorination of the guest, a reaction driven by electron transfer from host to excited guest. The main photoproducts contain a naphthyl group covalently attached to the host framework. The results may lead to new approaches for remediating water contaminated with chlorinated aromatic compounds.
Keywords
Photochemistry , dehalogenation , aryl halides , Complexes
Journal title
Chemosphere
Serial Year
2000
Journal title
Chemosphere
Record number
735033
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