Title of article
Phenol photonitration upon UV irradiation of nitrite in aqueous solution I: Effects of oxygen and 2-propanol Original Research Article
Author/Authors
Davide Vione، نويسنده , , Valter Maurino، نويسنده , , Claudio Minero، نويسنده , , Ezio Pelizzetti، نويسنده ,
Issue Information
روزنامه با شماره پیاپی سال 2001
Pages
10
From page
893
To page
902
Abstract
Nitrophenols are formed in aqueous solution upon UV irradiation of phenol and nitrite. The formation of nitrophenols is enhanced by dissolved oxygen and inhibited by the addition of 2-propanol. The mechanism of phenol photonitration involves both √NO2 (or N2O4), reacting with phenol, and 4-nitrosophenol, which is oxidised to 4-nitrophenol. A reaction scheme is proposed based on experimental results.
Keywords
nitrite , photolysis , Nitroaromatic compounds , Photochemical transformations
Journal title
Chemosphere
Serial Year
2001
Journal title
Chemosphere
Record number
735836
Link To Document