Numerical simulation of photochemical smog formation in Athens, Greece—A case study

High emission levels and the unfavourable topography are the main reasons for the alarming photochemical air pollution levels in Athens. An analysis of available air quality data proves that air pollution levels in Athens are largely affected by local wind circulation systems. The most frequent of these systems is dominated by the phenomenon of the sea breeze. Severe air pollution episodes occur, however, primarily under synoptic situations leading to stagnant conditions in the atmosphere over Athens. Photosmog formation in the Athens Basin is studied with the photochemical dispersion model MARS. The implicit solution algorithm incorporated in MARS is characterized by a variable time increment and a variable order. This solver allows avoiding unnecessary operator splitting by a coupled treatment of vertical diffusion and chemical kinetics. In this paper, MARS is used to analyse the situation on 25 May 1990, a day for which very high air pollution levels were reported in Athens. The simulation results elucidate the characteristics of a photosmog episode under stagnant conditions in Athens. In general, the model results reproduce satisfactorily the observed air pollution patterns.