• Title of article

    Observations on the reactivity of thiyl radicals derived from 3,6-epidithiodiketopiperazine-2,5-diones and related congeners

  • Author/Authors

    S.T. Hilton، نويسنده , , W.B. Motherwell، نويسنده , , P. Potier، نويسنده , , C. Pradet، نويسنده , , D.L. Selwood، نويسنده ,

  • Issue Information
    روزنامه با شماره پیاپی سال 2005
  • Pages
    4
  • From page
    2239
  • To page
    2242
  • Abstract
    A range of thiyl radicals derived from the reduced form of epidithiodiketopiperazines (ETPs) act as polarity reversal catalysts for the hydrosilylation of an enol lactone but not for H-atom abstraction from a model ribose ester.
  • Keywords
    Thiyl radicals , Epidithiodiketopiperazines , Polarity reversal catalysis , Mechanism , DNA cleavage
  • Journal title
    Bioorganic & Medicinal Chemistry Letters
  • Serial Year
    2005
  • Journal title
    Bioorganic & Medicinal Chemistry Letters
  • Record number

    795565