Correlation between chemical vapor deposited diamond and carbon fibers substrates

Diamond film formation has been studied on carbon felts (CF) substrates produced from polyacrylonitrile precursor, at different heat treatment temperatures (HTT). Scanning electron microscopy images have revealed a polycrystalline and preferential (111) diamond film covering the whole CF surface, even for deeper planes. The average grain size increased from 3.0 up to 6.0 lm for films grown on CF treated between 1000 and 2000 C. This behavior may be attributed to different contributions associated to the facility to extract carbons atoms from CF substrate. For CF treated at lower HTT, higher carbon atoms amount will promote higher nucleation density on diamond films and consequently a smaller grain size. Raman spectroscopy indicated good quality diamond films and the lower amount of graphitic phase was observed for diamond grown on CF obtained at 2000 C HTT. The microstructural properties of the CF were obtained by X-ray diffraction (XRD) and show a strong dependence with HTT.