Correlation between fracture toughness and microstructure of seeded silicon nitride ceramics

Microstructure development and fracture toughness of Si3N4 composites were studied in the presence of seeds and Al2O3 + Y2O3 as sintering aids. The elongated b-Si3N4 seeds were introduced into two different a-Si3N4 matrix powders; one was the ultra fine powder matrix and the other was the coarse powder matrix. The amount of seeds varied from 0 to 6 wt%. The grain growth inhibition and the mechanism of toughening were discussed and correlated with microstructure. The maximum fracture toughness of 9.0 MPa m1/2 was obtained for ultra fine powder with 5 wt% seeds hot pressed at 1,700 C for 6 h.