• Title of article

    Absolute line intensities for carbonyl sulfide from 827 to 2939 cmK1

  • Author/Authors

    J. Vander Auwera، نويسنده ,

  • Issue Information
    روزنامه با شماره پیاپی سال 2006
  • Pages
    8
  • From page
    134
  • To page
    141
  • Abstract
    Using a total of 18 unapodized high-resolution (MOPDZ300 and 450 cm) Fourier transform absorption spectra of carbonyl sulfide (P![Z 14.3–60,600 Pa!cm, TZ296.0 K), we measured 1340 absolute line intensities in 8 bands ðn1Cn12 Kn12 ; 2n02 ; 2n1; n1C2n02 ; 4n02 ; n3; n12 Cn3K n12 ; n1Cn3Þ of the main isotopologue, located between 827 and 2939 cmK1. In addition, we measured 307 absolute line intensities in the n3 fundamental band of 16O12C34S and 16O13C32S, observed near 2061.45 and 2009.23 cmK1, respectively. The observed Herman–Wallis dependences are in most cases reproduced by the global model of OCS [E. Rbaihi, A. Belafhal, J. Vander Auwera, S. Naı¨m, and A. Fayt, J. Mol. Spectrosc., 191:32–44, 1998]. The pressure self-broadening parameter was also measured up to JZ83. q 2005 Elsevier B.V. All rights reserved.
  • Keywords
    Absolute intensities , Infrared , Self-broadening , Transition dipole moments , Carbonyl sulfide
  • Journal title
    Journal of Molecular Structure
  • Serial Year
    2006
  • Journal title
    Journal of Molecular Structure
  • Record number

    845219