Isotopic, trace element and nutrient characterization of coastal waters from Ubatuba inner shelf area, south-eastern Brazil

Stable isotopes, tritium, radium isotopes, radon, trace elements and nutrients data were collected during two sampling campaigns in the Ubatuba coastal area (south-eastern Brazil) with the aim of investigating submarine groundwater discharge (SGD) in the region. The isotopic composition (dD, d18O, 3H) of submarine waters was characterised by significant variability and heavy isotope enrichment. The stable isotopes and tritium data showed good separation of groundwater and seawater groups. The contribution of groundwater in submarine waters varied from a few % to 17%. Spatial distribution of 222Rn activity concentration in surface seawater revealed changes between 50 and 200 Bq m 3 which were in opposite relationship with observed salinities. Time series measurements of 222Rn activity concentration in Flamengo Bay (from 1 to 5 kBq m 3), obtained by in situ underwater gamma-spectrometry showed a negative correlation between the 222Rn activity concentration and tide/salinity. This may be caused by sea level changes as tide effects induce variations of hydraulic gradients, which increase 222Rn concentration during lower sea level, and opposite, during high tides where the 222Rn activity concentration is smaller. The estimated SGD fluxes varied during 22e26 November between 8 and 40 cm d 1, with an average value of 21 cm d 1 (the unit is cm3/cm2 per day). The radium isotopes and nutrient data showed scattered distributions with offshore distance and salinity, which implies that in a complex coast with many small bays and islands, the area has been influenced by local currents and groundwatereseawater mixing. SGD in the Ubatuba area is fed by coastal contaminated groundwater and re-circulated seawater (with small admixtures of groundwater), which claims for potential environmental concern with implications on the management of freshwater resources in the region.