Title of article
Hydrogenation of fructose on Ru/C catalysts Original Research Article
Author/Authors
Annemieke W Heinen، نويسنده , , Joop A. Peters، نويسنده , , Herman van Bekkum، نويسنده ,
Issue Information
دوهفته نامه با شماره پیاپی سال 2000
Pages
9
From page
449
To page
457
Abstract
The hydrogenation of d-fructose on Ru/C catalysts was studied. Under the conditions applied (1 bar H2, 72 °C), the furanose forms of d-fructose react, while the pyranose forms do not. However, all anomers adsorb with comparable strength on the surface. The reaction rate is controlled by product inhibition. The selectivity to d-mannitol can be increased from 47 to 63% by promotion of Pd/C and Pt/C catalysts with Sn.
Keywords
Activated carbon , TIN , d-Glucitol , promoter , d-Mannitol
Journal title
Carbohydrate Research
Serial Year
2000
Journal title
Carbohydrate Research
Record number
962758
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