• Title of article

    Triazole-fused sugars from nitroalkene-containing C-glycosides by a tandem 1,3-dipolar cycloaddition and intramolecular Michael addition

  • Author/Authors

    Wei Zou، نويسنده , , Milan Bhasin، نويسنده , , Kannan Vembaiyan، نويسنده , , Dean T. Williams، نويسنده ,

  • Issue Information
    دوهفته نامه با شماره پیاپی سال 2009
  • Pages
    4
  • From page
    1024
  • To page
    1027
  • Abstract
    A synthetic method to triazole-fused sugars by treatment of nitroalkene-containing C-glycosides with sodium azide is described. Initial experiments conducted at room temperature gave only the 1,3-dipolar cycloaddition products. However, at elevated reaction temperature the tandem β-elimination/cycloaddition/Michael addition yielded 1,5-disubstituted triazole-fused sugars.
  • Keywords
    Triazole , C-Glycoside , Nitroalkene , Michael addition , Cycloaddition , Synthesis
  • Journal title
    Carbohydrate Research
  • Serial Year
    2009
  • Journal title
    Carbohydrate Research
  • Record number

    966413