• شماره ركورد
    84758
  • عنوان مقاله

    Synthesis of N2O2S2-Schiff base Ligand and Using it to Transport Cu2+ Through Bulk Liquid Membrane

  • پديد آورندگان

    Al Zoubi, W. Damascus University - Faculty of Sciences - Department of Chemistry, Syria , Kandil, F. Damascus University - Faculty of Sciences - Department of Chemistry, Syria

  • از صفحه
    105
  • تا صفحه
    120
  • تعداد صفحه
    16
  • چكيده عربي
    لا يمكن إدراج ملخص المقال
  • چكيده لاتين
    New Schiff base (H2L) containing nitrogen-sulfur-oxygen atoms was synthesized by reaction of α,α -bis(5- Bromo-2-carboxyaldehyde phenoxy)-1.4- xylene with aminothiophenol. Transport of copper ion across a bulk chloroform membrane containing Schiff base ligand (H2L) as carrier has been studied. The parameters influencing the transport efficiency such as composition of receiving phase, pH of the feed phase, carrier concentration in the membrane, EDTA concentration in the receiving phase, effect of temperature and time dependency of the process were studied and discussed. The amount of copper transport through the liquid membrane after 48 min., arrived to 100% at temperature 58°C.
  • كليدواژه
    N2O2S2 , type Schiff base ligands , Bulk liquid membrane , Copper (II) ions separation
  • سال انتشار
    2012
  • عنوان نشريه
    مجله جامعه دمشق للعلوم الاساسيه
  • عنوان نشريه
    مجله جامعه دمشق للعلوم الاساسيه