Author/Authors
Dede, Bülent Süleyman Demirel Üniversitesi - Fen-Edebiyat Fakültesi - Kimya Bölümü, Turkey , Korkmaz, Hanife Süleyman Demirel Üniversitesi - Fen-Edebiyat Fakültesi - Kimya Bölümü, Turkey
Title Of Article
Oksim Grubu İçeren Dinükleer Fe(II) ve Mn(II) Komplekslerinin Sentezi, Karakterizasyonu, Katalaz ve Katekolaz Enzim Aktivitelerinin İncelenmesi
شماره ركورد
35993
Abstract
In this study, dinuclear iron(II) and manganese(II) complexes were synthesized using two different ligands containing oxime group. These new complexes have been characterized by elemental analyses, ICP-OES, FT-IR spectra, TG, magnetic susceptibility and conductivity measurements. The results suggest that the dinuclear complexes of H2L1 and H4L2 have a metal:ligand ratio of 2:2 and 2:1, respectively. Furthermore complexes were each tested both for their ability to catalyse the disproportionation of hydrogen peroxide in the presence of the added base imidazole and oxidation reaction of 3,5-di-tert-butylcatechol to the 3,5-di-tert-butylquinone presence of O2. It was found that all complexes exhibited good both catalase and catecholase activity.
From Page
163
NaturalLanguageKeyword
oxime , complex , catalase , catecholase , enzyme
JournalTitle
Süleyman Demirel University Faculty of Arts and Science Journal of Science
To Page
175
JournalTitle
Süleyman Demirel University Faculty of Arts and Science Journal of Science
Link To Document