DocumentCode
1060022
Title
Bond-orbital model for second-order susceptibilities
Author
Choy, Michael M. ; Ciraci, Salim ; Byer, Robert L.
Author_Institution
Stanford University, Stanford, CA, USA
Volume
11
Issue
1
fYear
1975
fDate
1/1/1975 12:00:00 AM
Firstpage
40
Lastpage
45
Abstract
The bond-orbital model (BOM) for tetrahedral compounds is used self-consistently to calculate the second-order susceptibility. No adjustable parameters are used and agreement with experiment is good. The origin of the nonlinearity arises from a charge transfer as a result of the asymmetric polar energy between the anion and the cation. The model correctly predicts an optimum polarity to maximize second-order susceptibilities.
Keywords
Bills of materials; Bonding; Equations; Nonlinear optical devices; Nonlinear optics; Optical materials; Orbital calculations; Oscillators; Predictive models; Wave functions;
fLanguage
English
Journal_Title
Quantum Electronics, IEEE Journal of
Publisher
ieee
ISSN
0018-9197
Type
jour
DOI
10.1109/JQE.1975.1068515
Filename
1068515
Link To Document