DocumentCode
1432976
Title
Influence of heat treatment temperature on the electro-catalytic behaviour of nanostructure RuO2-TiO2 coating for the chlorine evolution reaction
Author
Moradi, Farshad ; Dehghanian, C.
Author_Institution
Sch. of Metall. & Mater. Eng., Univ. of Tehran, Tehran, Iran
Volume
7
Issue
1
fYear
2012
fDate
1/1/2012 12:00:00 AM
Firstpage
37
Lastpage
40
Abstract
60RuO2-40TiO2 coating was deposited on titanium substrate by the thermal decomposition of chloride solution. The mixed oxide thin film was prepared in different heat treatment temperatures. The effect of heat treatment temperature on the electro-catalytic performance of the mixed oxide coating during chlorine evolution was evaluated. Coated anodes were studied by field emission scanning electron microscopy and X-ray diffraction. Chlorine evolution was studied in 5 M NaCl solution by potentiodynamic current potential curves. Heat treatment temperature has the most significant effect on electro-catalytic activity of the coating. High heat treatment temperature deteriorates electro-catalytic performance of coating for chlorine evolution reaction. Low ratio of the active 101 crystallographic faces observed in high temperature can reduce the current density for gas evolution.
Keywords
X-ray diffraction; anodes; catalysis; coatings; current density; electrochemistry; field emission electron microscopy; heat treatment; nanostructured materials; pyrolysis; ruthenium compounds; scanning electron microscopy; thin films; titanium; titanium compounds; RuO2-TiO2-Ti; X-ray diffraction; anodes; chlorine evolution reaction; current density; electrocatalytic behaviour; field emission scanning electron microscopy; gas evolution; heat treatment temperature; nanostructure coating; potentiodynamic current potential curves; thermal decomposition; thin film;
fLanguage
English
Journal_Title
Micro & Nano Letters, IET
Publisher
iet
ISSN
1750-0443
Type
jour
DOI
10.1049/mnl.2011.0529
Filename
6140916
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