The routes towards teree dimensional fully conjugated conducting polymers : 1-preparation of the kit of monomers

Summary form only given. The aim of this study is to prepare fully conjugated architectures, the dimensionality of which is d > 2. Among the different possible ways of elaboration of these kinds of polymers, we have decided to perform the copolymerization of 3-n-octylthiophene with fully conjugated reticulation points containing three thienyl groups. In this first communication, we report the preparation of the different reticulation points and the preliminary copolymerization tests. These tests are performed on D-labeled reticulation points with a relatively high ratio : [reticulation point]/[3-n octylthiophenel in order to be able to observe the reactivity of the reticulation points during the copolymerization.