• DocumentCode
    311785
  • Title

    Preparation and properties of Bi4Ti3O12 thin films by electron cyclotron resonance sputtering

  • Author

    Maiwa, Hiroshi ; Ichinose, Noboru

  • Author_Institution
    Dept. of Mater. Sci. & Ceramic Technol., Shonan Inst. of Technol., Fujisawa, Japan
  • Volume
    1
  • fYear
    1996
  • fDate
    18-21 Aug 1996
  • Firstpage
    455
  • Abstract
    Thin films of ferroelectric Bi4Ti3O12 were deposited on Pt- or Ir-coated oxidized Si substrate by electron cyclotron resonance (ECR) sputtering using ceramic targets. Crystal structure and dielectric properties of the films were investigated as functions of sputtering conditions such as substrate temperature, sputtering gas pressure and used substrate. Using a target with excess Bi content compared to stoichiometric composition was required to compensate Bi re-evaporation from the substrate and to obtain a perovskite single phase at 600°C. (117)-oriented films exhibited ferroelectric hysteresis loops. The remanent polarization and coercive field of the Bi4Ti3O12 films on Pt/SiO2/Si were 10.9 μC/cm2 and 139 kV/cm, respectively. Those of the films on Ir/SiO2/Si were 3.6 μC/cm2 and 99 kV/cm, respectively
  • Keywords
    bismuth compounds; dielectric hysteresis; ferroelectric thin films; sputter deposition; 600 C; Bi4Ti3O12; coercive field; crystal structure; dielectric properties; electron cyclotron resonance sputtering; ferroelectric thin film; hysteresis loop; perovskite phase; remanent polarization; Bismuth; Cyclotrons; Dielectric substrates; Dielectric thin films; Electrons; Ferroelectric films; Ferroelectric materials; Semiconductor films; Semiconductor thin films; Sputtering;
  • fLanguage
    English
  • Publisher
    ieee
  • Conference_Titel
    Applications of Ferroelectrics, 1996. ISAF '96., Proceedings of the Tenth IEEE International Symposium on
  • Conference_Location
    East Brunswick, NJ
  • Print_ISBN
    0-7803-3355-1
  • Type

    conf

  • DOI
    10.1109/ISAF.1996.602787
  • Filename
    602787