Modeling, estimation, and control challenges for lithium-ion batteries

Increasing demand for hybrid electric vehicles (HEV), plug-in hybrid electric vehicles (PHEV) and electric vehicles (EV) has forced battery manufacturers to consider energy storage systems that are better than contemporary lead-acid batteries. Currently, lithium-ion (Li-ion) batteries are believed to be the most promising battery system for HEV, PHEV and EV applications. However, designing a battery management system for Li-ion batteries that can guarantee safe and reliable operation is a challenge, since aging and other performance degrading mechanisms are not sufficiently well understood. As a first step to address these problems, we analyze an existing electrochemical model from the literature. Our aim is to present this model from a systems & controls perspective, and to bring forth the research challenges involved in modeling, estimation and control of Li-ion batteries. Additionally, we present a novel compact form of this model that can be used to study the Li-ion battery. We use this reformulated model to derive a simple approximated model, commonly known as the single particle model, and also identify the limitations of this approximation.