• DocumentCode
    3368226
  • Title

    Phase formation in the flux systems K2O-P2O5-Fe2O3-MIIO-MoO3

  • Author

    Yatskin, M.M. ; Zatovsky, I.V. ; Strutynska, N.Yu. ; Baumer, V.N. ; Slobodyanik, N.S.

  • Author_Institution
    Kiev National Taras Shevchenko University, Chemical department, Kyiv, Ukraine
  • fYear
    2012
  • fDate
    3-7 Sept. 2012
  • Firstpage
    109
  • Lastpage
    110
  • Abstract
    KMg0.09Fe1.91(PO4)2 is isotypic with KMIIFe(PO4)2 (MII - Fe, Cu) (monoclinic system, space group P 21/n). The framework is built up from [FeO5] and [Fe(Mg)O6] polyhedra sharing vertices, edges and connected by two types of bridging PO4 tetrahedra. The K atoms are nine-coordinated and are located in hexagonal channels running along the direction of c-axis.
  • Keywords
    Compounds; Crystals; Glass; Iron; Solids; BVS (Bond Valence Sums); complex phosphates; molten system; substitution;
  • fLanguage
    English
  • Publisher
    ieee
  • Conference_Titel
    Oxide Materials for Electronic Engineering (OMEE), 2012 IEEE International Conference on
  • Conference_Location
    Lviv, Ukraine
  • Print_ISBN
    978-1-4673-4491-3
  • Type

    conf

  • DOI
    10.1109/OMEE.2012.6464778
  • Filename
    6464778