DocumentCode
3368226
Title
Phase formation in the flux systems K2 O-P2 O5 -Fe2 O3 -MIIO-MoO3
Author
Yatskin, M.M. ; Zatovsky, I.V. ; Strutynska, N.Yu. ; Baumer, V.N. ; Slobodyanik, N.S.
Author_Institution
Kiev National Taras Shevchenko University, Chemical department, Kyiv, Ukraine
fYear
2012
fDate
3-7 Sept. 2012
Firstpage
109
Lastpage
110
Abstract
KMg0.09 Fe1.91 (PO4 )2 is isotypic with KMIIFe(PO4 )2 (MII - Fe, Cu) (monoclinic system, space group P 21 /n). The framework is built up from [FeO5 ] and [Fe(Mg)O6 ] polyhedra sharing vertices, edges and connected by two types of bridging PO4 tetrahedra. The K atoms are nine-coordinated and are located in hexagonal channels running along the direction of c-axis.
Keywords
Compounds; Crystals; Glass; Iron; Solids; BVS (Bond Valence Sums); complex phosphates; molten system; substitution;
fLanguage
English
Publisher
ieee
Conference_Titel
Oxide Materials for Electronic Engineering (OMEE), 2012 IEEE International Conference on
Conference_Location
Lviv, Ukraine
Print_ISBN
978-1-4673-4491-3
Type
conf
DOI
10.1109/OMEE.2012.6464778
Filename
6464778
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