• DocumentCode
    3749431
  • Title

    Thermodynamic model for the compensation law in polymers

  • Author

    Jean-Pierre Crine

  • Author_Institution
    Institut de recherche d´Hydro-Qué
  • fYear
    1983
  • fDate
    7/1/1983 12:00:00 AM
  • Firstpage
    61
  • Lastpage
    64
  • Abstract
    The linear relation between ΔH≠ and ΔS≠ (the compensation law) has been verified for relaxations in several polymers. The predicted free energy has discontinuities corresponding to actual relaxation peaks. While it is more correct to deduce ΔH≠ and ΔS≠ from a log (υ/T) vs 1/T plot rather than from a log υ vs 1/T plot, in no way this gives the real activated values because ΔG* is usually neglected.
  • Keywords
    "Plastics","Mathematical model","Positron emission tomography","Chlorine","Polymers"
  • Publisher
    ieee
  • Conference_Titel
    Conduction and Breakdown in Solid Dielectrics, Proceedings of First International Conference on
  • Type

    conf

  • DOI
    10.1109/ICSD.1983.7411483
  • Filename
    7411483
    • Link To Document
    https://search.isc.ac/dl/search/defaultta.aspx?DTC=49&DC=3749431