Abstract :
Two-photon polymerisation of photo-sensitive materials allows the fabrication of three dimensional micro- and nano-structures for photonic,
electronic and micro-system applications. However the usable process window and the applicability of this fabrication technique is significantly
determined by the properties of the photo-sensitive material employed. In this study investigation of a custom inorganic–organic hybrid system,
cross-linked by a two-photon induced process, is described. The material was produced by sol–gel synthesis using a silicon alkoxide species that
also possessed methacrylate functionality. Stabilized zirconium alkoxide precursors were added to the precursor solution in order to reduce drying
times and impart enhanced mechanical stability to deposited films. This enabled dry films to be used in the polymerisation process. A structural,
optical and mechanical analysis of the optimised sol–gel material is presented. A Ti:sapphire laser with 80 MHz repetition rate, 100 fs pulse
duration and 795 nm is used. The influence of both material system and laser processing parameters including: laser power, photo-initiator
concentration and zirconium loading, on achievable micro-structure and size is presented
