Color-tunable magnetic and luminescent hybrid nanoparticles: Synthesis, optical and magnetic properties

A facile method for synthesizing color-tunable magnetic and luminescent hybrid bifunctional nanoparticles is presented. A series of CdSe/ZnS core–shell quantum dots (QDs) with different sizes were successfully fabricated and self-assembled to Fe3O4 magnetic nanoparticles (MNP), which were subsequently coated with a polyethyleneimine (PEI) layer to prevent large aggregates. The hydrophobic QDs capped with trioctylphosphine oxide (TOPO) formed a coating surrounding MNP, and were transferred into hydrophilic phase by PEI with high efficiency. The samples were characterized by TEM, FT-IR, XRD, EDS, UV–vis spectrophotometer, fluorescent spectrophotometer and PPMS. Results show that the original properties of the nanoparticles were well-preserved in the hybrid structure. All MNP-QDs hybrid nanoparticles showed paramagnetic behavior and the nanocomposites were still highly luminescent with no shift in the PL peak position.